14 matches (6W 2D 6L), goals: 18-19
World Cup 1966, Copa Hispanidad 1972, Copa Hispanidad 1974
| 07 DEC 1952 | Spain - Argentina | 0:1 | Friendly |
| 05 JUL 1953 | Argentina - Spain | 1:0 | Friendly |
| 24 JUL 1960 | Argentina - Spain | 2:0 | Friendly |
| 11 JUN 1961 | Spain - Argentina | 2:0 | Friendly |
| 13 JUL 1966 | Argentina - Spain | 2:1 | World Cup |
| 11 OCT 1972 | Spain - Argentina | 1:0 | Copa Hispanidad |
| 12 OCT 1974 | Argentina - Spain | 1:1 | Copa Hispanidad |
| 12 OCT 1988 | Spain - Argentina | 1:1 | Friendly |
| 20 SEP 1995 | Spain - Argentina | 2:1 | Friendly |
| 17 NOV 1999 | Spain - Argentina | 0:2 | Friendly |
| 11 OCT 2006 | Spain - Argentina | 2:1 | Friendly |
| 14 NOV 2009 | Spain - Argentina | 2:1 | Friendly |
| 07 SEP 2010 | Argentina - Spain | 4:1 | Friendly |
| 27 MAR 2018 | Spain - Argentina | 6:1 | Friendly |